3-({[Bis(2-methylpropyl)carbamothioyl]amino}carbonyl)benzamide
نویسندگان
چکیده
In the title compound, C17H25N3O2S, the terminal and central amide groups are, respectively, twisted and coplanar with the attached benzene ring [O-C-C-C torsion angles = 22.7 (3) and 5.4 (3)°]. In the central part of the mol-ecule, the amide and thio-amide residues are approximately perpendicular [C-N-C-S torsion angle = -104.98 (18)°]. Supra-molecular layers with a zigzag topology are formed in the crystal packing by N-H⋯O, N-H⋯S and C-H⋯O inter-actions; these stack along c, being separated by hydro-phobic inter-actions.
منابع مشابه
1-[3-({[Bis(2-methylpropyl)carbamothioyl]amino}carbonyl)benzoyl]-3,3-bis(2-methylpropyl)thiourea
The title compound, C26H42N4O2S2, adopts a shallow U-shape as both pendant arms of the 1,3-substituted benzene ring are orientated in the same direction. The thione S atoms lie to the same side of the benzene ring and the carbonyl O atoms to the other. The most prominent feature of the crystal packing is the formation of inversion dimers mediated by N-H⋯S hydrogen bonds. One of the 2-methyl-pro...
متن کاملCrystal structures of N-[(4-phenylthiazol-2-yl)carbamothioyl]benzamide and N-{[4-(4-bromophenyl)thiazol-2-yl]carbamothioyl}benzamide from synchrotron X-ray diffraction
The title compounds, C17H13N3OS2, (I), and C17H12BrN3OS2, (II), are potential active pharmaceutical ingredients. Compound (I) comprises two almost planar fragments. The first is the central (carbamo-thio-yl)amide (r.m.s. deviation = 0.038 Å), and the second consists of the thia-zole and two phenyl rings (r.m.s. deviation = 0.053 Å). The dihedral angle between these planes is 15.17 (5)°. Unlike ...
متن کاملCrystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide
In the title compound, C15H15N3OS, there is an intra-molecular N-H⋯O hydrogen bond and an intra-molecular C-H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol-ecule. The mol-ecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds, forming inve...
متن کاملIon-Selective Carbon Paste Electrode Based on 2-Amino-N-benzthioazolyl Benzamide (ABTB) for Determination of Copper (II) by Potentiometric Method
2-Amino-N-benzthioazolyl benzamide (ABTB) was synthesized, characterized and used for thefabrication of a potentiometric sensor for Cu2+ metal ions. The electrode exhibits linear response to Cu(II) over a wide concentration range (4.79×10 -8 – 1.85×10 -1 M) with Nernstian slope of 30 ± 1.5 mVper decade. The electrode can be used in the pH range from 2 to 9. It has a fast response time of about1...
متن کامل3-{[(Dibenzylcarbamothioyl)amino]carbonyl}benzamide
Two independent mol-ecules with quite similar conformations, A and B, comprise the asymmetric unit of the title compound, C23H21N3O2S. The terminal amide substituent is coplanar with the attached benzene ring [the O-C-C-C torsion angles are 174.0 (2) (A) and 6.3 (3)° (B)]. In the same way, the central amide group [C-C-C-O = 7.8 (3) (A) and 11.5 (3)° (B)] is approximately coplanar with the ring ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013